ISO 14404:2024 Carbon Balance Methodology

Understanding the standardized approach for calculating carbon inputs and outputs in blast furnace operations to optimize efficiency and reduce emissions.

Introduction to Carbon Balance

The carbon balance methodology defined in ISO 14404:2024 provides a systematic approach for calculating greenhouse gas emissions from steel production through blast furnace routes.

Mass Balance Principle

The fundamental concept that carbon input must equal carbon output, accounting for all transformation processes within the system boundary.

System Boundaries

Clearly defined boundaries for the blast furnace process, including all material inputs, energy carriers, and emission outputs.

Standardized Calculation

Uniform methodology ensuring comparability across different facilities and enabling accurate benchmarking of performance.

Carbon Balance Methodology

The step-by-step approach to calculating carbon flows according to ISO 14404:2024 standards.

1

Define System Boundaries

Establish the physical and process boundaries for the carbon balance calculation, typically including the blast furnace proper and its direct auxiliaries.

System Boundary Includes:

  • Blast furnace proper
  • Hot blast stoves
  • Raw material handling
  • Top gas recovery system
2

Identify Carbon Inputs

Quantify all carbon-containing materials entering the system boundary, including both reducing agents and other carbon sources.

Carbon Input Formula:

Cin = Ccoke + CPCI + Cother

Where Ccoke is carbon from metallurgical coke, CPCI is carbon from pulverized coal injection, and Cother includes other carbon sources.

3

Identify Carbon Outputs

Account for all carbon leaving the system boundary, including products, by-products, and emissions.

Carbon Output Formula:

Cout = CHM + Cslag + Cgas + Cdust + Cother

Where CHM is carbon in hot metal, Cslag is carbon in slag, Cgas is carbon in top gas, and Cdust is carbon in dust emissions.

4

Calculate Carbon Balance

Apply the mass balance principle to ensure carbon inputs equal carbon outputs, accounting for any accumulation within the system.

Carbon Balance Equation:

Cin = Cout + ΔCstorage

Where ΔCstorage represents changes in carbon stored within the system (typically negligible over measurement periods).

Carbon Flow in Blast Furnace Operations

Coke

895 kgC/thm

Blast Furnace

Carbon Transformation

Hot Metal

453 kgC/thm

PCI Coal

142 kgC/thm

Top Gas

318 kgC/thm

Slag & Dust

26 kgC/thm

Calculation Example

A practical example demonstrating the carbon balance calculation for a typical blast furnace operation.

Carbon Balance Calculation for BF-01

Based on operational data from a 24-hour period for production of 10,000 tonnes of hot metal.

Carbon Inputs Quantity Carbon Content Total Carbon
Metallurgical Coke 4,200 t 85% 3,570 tC
PCI Coal 1,450 t 75% 1,088 tC
Other Carbon Sources 150 t 80% 120 tC
Total Carbon Input 4,778 tC
Carbon Outputs Quantity Carbon Content Total Carbon
Hot Metal 10,000 t 4.5% 450 tC
Top Gas 18,500,000 Nm³ 22% CO₂ 3,640 tC
Slag 2,800 t 0.5% 14 tC
Dust & Losses 120 t 10% 12 tC
Total Carbon Output 4,116 tC

Carbon Balance Result

Carbon Input: 4,778 tC | Carbon Output: 4,116 tC

Carbon Balance Discrepancy: 662 tC (13.9% of input)

This discrepancy indicates measurement inaccuracies or unaccounted carbon flows that require investigation.

Key Performance Indicators

Carbon efficiency, specific emission factor, and carbon utilization rate are critical KPIs derived from carbon balance calculations.

Reporting Requirements

ISO 14404:2024 specifies the data quality, documentation, and reporting standards for carbon balance calculations.

Optimization Opportunities

Carbon balance analysis identifies opportunities for process improvements, energy savings, and emission reductions.